Paloma has found herself in the running for the big award of the ceremony - Best Album, for her second album Fall From Grace.
The beauty is up against Emeli Sande's Our Version Of Events, Alt-J's An Awesome Wave, the Mumford release Babel and Plan B's Ill Manors.
Paloma told MailOnline she was 'ecstatic' to be nominated for the gong but doesn't back herself to actually pick up the award.
She said: 'I feel ecstatic to be nominated, it's amazing. But I really don't think I'll win. I kind of hope I don't in a way so then I don't have to prepare a winner's speech. I'm going to practice a really overjoyed face for when someone else wins!'
Rita, 22, also opted for a yellow-beige sequin-embellished gown, with a plunging neckline by Diane Von Furstenberg which she teamed with nude Christian Louboutin pointed heels.
The R.I.P singer told MailOnline having three nominations, including two for best song is 'amazing'.
Backing British fashion: Paloma looked stunning in the Vivienne Westwood gown, which she teamed with a feathered headpiece
Shining star: Rita covered up in sequin-covered gown by Diane Von Furstenberg
'It's been a long journey to get here and a lot of hard work.'
Paloma added: 'I'd love to see Led Zeppelin win the lifetime achievement award.'
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